References: Abdel Bar‚ F.M.‚ Khanfar‚ M.A.‚ Elnagar‚ A.Y.‚ Badria‚ F.A.‚ Zaghloul‚ A.M.‚ Ahmad‚ K.F.‚ . . . ‚ El Sayed‚ K.A. (2010). Design and pharmacophore modeling of biaryl methyl eugenol analogs as breast cancer invasion inhibitors. Bioorganic & Medicinal Chemistry‚ 18‚ 496–507. Aboutabl‚ E.A.‚ El Tohamy‚ S.F.‚ De Footer‚ H.L.‚ & De Buyck‚ L.F. (1991). A comparative study of the essential oils from three Melaleuca species growing
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Preparation of N‚N-Diethyl-m-toluamide (DEET) and its Identification by IR and NMR Spectroscopy Eim A. Chemist CHEM 304 July 10‚ 2005 INTRODUCTION N‚N-Diethyl-m-toluamide (DEET) is the active ingredient in many insect repellants.1 In this experiment‚ DEET will be prepared from m-toluic acid through the intermediate acid chloride and then identified by its IR and proton NMR spectra. The overall reaction is a series of two acyl substitutions and is shown in Scheme 1 below: [pic] Scheme
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Electron Spin Nuclear Magnetic Resonance (NMR) Spectroscopy Organic Chemistry BCH3015 • Electron spin is quantized. • The spin quantum number ms has only two allowed values: ms = +½ or –½ • The two directions of spin create oppositely spin create oppositely directed magnetic fields. fields. 61 Proton Spin Organic Chemistry BCH3015 62 Nuclear Spin States • A proton (the nucleus of a 1H atom) also possesses spin. For each nucleus having the spin quantum number
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different kinds of protons are present in each of the following compounds? A. a: 4; b: 4; c: 4 B. a: 4; b: 4; c: 5 C. a: 3; b: 3; c: 5 D. a: 3; b: 4; c: 5 E. a: 4; b: 3; c: 5 2. Which of the labeled hydrogens absorbs furthest upfield in the NMR? A. Ha B. Hb C. Hc D. Hd E. He 3. Which of the following compounds does not give a singlet in its NMR spectrum? A. A B. B C. C 4. Which of the circled protons in the molecules below would absorb furthest downfield in the NMR? A. A B
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produce the E and Z phenylcinnamic acid. The mechanism for this reaction can be seen in figure 1. Table 1 includes all spectroscopic values for both E and Z isomers of phenylcinnamic acid. The IRs for both E and Z can be seen in figure 2 and 3. The NMR can be seen in figure 4 and 5‚ while the mass spec can be seen in figure 6. According to the experimental IR spectroscopy for the E isomer of phenylcinnamic acid the peaks of the wavenumber were at 2952‚ 2518 1672 and 1426 cm-1. The peak at 2952 presents
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The product was then purified by flash chromatography and analyzed by IR‚ 1H NMR and 13C NMR. The synthesis of piperonylontitrile was successful. There was a yield of a pale yellow crystal of 36%. The average recovery is 51% with there being a range from 0-94 %1. A reason for a smaller yield than notable reported could have been due
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Atomic Masses of atoms & molecules Mass number & atomic number Atomic structure (neutrons‚ protons & electrons) Mole concept & conversion Avogadro’s concept Empirical & molecular formulae Isotopes FHSC1114 Physical Chemistry Centre for Foundation Studies‚ UTAR Objectives To define relative atomic masses of atoms & molecules To define & determine mass no. & atomic no. To determine no. of neutrons‚ protons & electrons To understand mole concept & Avogadro’s concept To determine the empirical
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org/jchemeduc NMR Kinetics of the SN2 Reaction between BuBr and I−: An Introductory Organic Chemistry Laboratory Exercise T. Andrew Mobley* Department of Chemistry‚ Grinnell College‚ Grinnell‚ Iowa 50112‚ United States S Supporting Information * ABSTRACT: A simple organic chemistry experiment is described that investigates the kinetics of the reaction between 1-bromobutane (BuBr) and iodide (I−) as followed by observing the disappearance of BuBr and the appearance of 1-iodobutane (BuI) using 1H NMR spectroscopy
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January 24‚ 2015 Discussion In this laboratory assignment‚ the spectroscopy data and molecular formula were given for 3 unknowns. An effort was made to conclusively identify these unknown samples using only the spectroscopy data‚ specifically 1H-NMR‚ 13C-NMR‚ and IR spectroscopy. Although mass spectrometry was given for the samples as well‚ its use was suggested only for confirmation‚ not identification‚ of the unknowns. Mass spectrometry was not included in the identification analysis of the compounds
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Synthesis of an Alkyl Halide: A Nucleophilic Substitution Reaction Unknown Letter: B 23 April 2013 Academic Integrity Statement: “Experimental data may be collected with other students in organic chemistry labs. However I understand that sharing information required for a lab report (including but not limited to word processing or spreadsheet files‚ calculations‚ graphs‚ conclusions and additional problems at the end of the lab report) with other students is a violation of the University
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