Preview

Carbon Nanotubes

Powerful Essays
Open Document
Open Document
9602 Words
Grammar
Grammar
Plagiarism
Plagiarism
Writing
Writing
Score
Score
Carbon Nanotubes
Composites Science and Technology 61 (2001) 1899–1912 www.elsevier.com/locate/compscitech

Advances in the science and technology of carbon nanotubes and their composites: a review
Erik T. Thostensona, Zhifeng Renb, Tsu-Wei Choua,* a Department of Mechanical Engineering and Center for Composite Materials, University of Delaware, Newark, DE 19716, USA b Department of Physics, Boston College, Chestnut Hill, MA 02167, USA Received 1 May 2001; received in revised form 19 June 2001; accepted 21 June 2001

Abstract Since their first observation nearly a decade ago by Iijima (Iijima S. Helical microtubules of graphitic carbon Nature. 1991; 354:56–8), carbon nanotubes have been the focus of considerable research. Numerous investigators have since reported remarkable physical and mechanical properties for this new form of carbon. From unique electronic properties and a thermal conductivity higher than diamond to mechanical properties where the stiffness, strength and resilience exceeds any current material, carbon nanotubes offer tremendous opportunities for the development of fundamentally new material systems. In particular, the exceptional mechanical properties of carbon nanotubes, combined with their low density, offer scope for the development of nanotubereinforced composite materials. The potential for nanocomposites reinforced with carbon tubes having extraordinary specific stiffness and strength represent tremendous opportunity for application in the 21st century. This paper provides a concise review of recent advances in carbon nanotubes and their composites. We examine the research work reported in the literature on the structure and processing of carbon nanotubes, as well as characterization and property modeling of carbon nanotubes and their composites. # 2001 Elsevier Science Ltd. All rights reserved.

1. Introduction In the mid 1980s, Smalley and co-workers at Rice University developed the chemistry of fullerenes [2]. Fullerenes are geometric cage-like



References: [1] Iijima S. Helical microtubules of graphitic carbon. Nature 1991; 354:56–8. [2] Kroto HW, Heath JR, O’Brien SC, Curl RF, Smalley RE. C60: Buckminsterfullerene. Nature 1985;318:162–3. [3] Chou T-W. Microstructural design of fiber composites. Cambridge, UK: Cambridge University Press, 1992. [4] Collins PG, Avouris P. Nanotubes for electronics. Scientific American 2000;283(6):62–9. [5] Fan S, Chapline MG, Franklin NR, Tombler TW, Cassell AM, Dai H. Self-oriented regular arrays of carbon nanotubes and their field emission properties. Science 1999;283:512–4. [6] Wong SS, Joselevich E, Woolley AT, Cheung CL, Lieber CM. Covalently functionalized nanotubes as nanometre-sized probes in chemistry and biology. Nature 1998;394:52–5. [7] Rueckes T, Kim K, Joselevich E, Tseng GY, Cheung C-L, Lieber CM. Carbon nanotube-based nonvolatile random access memory for molecular computing. Science 2000;289:94–7. [8] Yao Z, Postma HWC, Balents L, Dekker C. Carbon Nanotube Intramolecular Junctions. Nature 1999;402:273–6. [9] Dresselhaus MS, Dresselhaus G, Eklund PC. Science of fullerenes and carbon nanotubes. San Diego: Academic Press, 1996. [10] Yakobson BI, Brabec CJ, Bernholc J. Nanomechanics of carbon tubes: instabilities beyond linear range. Physical Review Letters 1996;76(14):2511–4. [11] Yakobson BI, Samsonidze G. Atomistic theory of mechanical relaxation in fullerene nanotubes. Carbon 2000;38(11-12):1675–80. [12] Nardelli MB, Yakobson BI, Bernholc J. Brittle and ductile behavior in carbon nanotubes. Physical Review Letters 1998; 81(21):4656–9. [13] Iijima S, Ichlhashi T. Single-shell carbon nanotubes of 1-nm diameter. Nature 1993;363:603–5. [14] Bethune DS, Kiang CH, Devries MS, Gorman G, Savoy R, Vazquez J, et al. Cobalt-catalyzed growth of carbon nanotubes with single-atomic-layer walls. Nature 1993;363:605–7. [15] Journet C, Maser WK, Bernier P, Loiseau A, de la Chapelle ML, Lefrant S, et al. Large-scale production of single-walled carbon nanotubes by the electric-arc technique. Nature 1997;388:756–8. E.T. Thostenson et al. / Composites Science and Technology 61 (2001) 1899–1912 [36] Salvetat JP, Briggs GAD, Bonard JM, Bacsa RR, Kulik AJ, Stockli T et al. Elastic and shear moduli of single-walled carbon ¨ nanotube ropes. Physical Review Letters 1999;82(5):944–7. [37] Walters DA, Ericson LM, Casavant MJ, Liu J, Colbert DT, Smith KA, et al. Elastic strain of freely suspended single-wall carbon nanotube ropes. Applied Physics Letters 1999;74(25):3803–5. [38] Yu MF, Lourie O, Dyer M, Moloni K, Kelly T. Strength and breaking mechanism of multi-walled carbon nanotubes under tensile load. Science 2000;287:637–40. [39] Yu MF, Files BS, Arepalli S, Ruoff RS. Tensile loading of ropes of single wall carbon nanotubes and their mechanical properties. Physical Review Letters 2000;84(24):5552–5. [40] Xie S, Li W, Pan Z, Chang B, Sun L. Mechanical and physical properties on carbon nanotube. Journal of Physics and Chemistry of Solids 2000;61(7):1153–8. [41] Falvo MR, Clary GJ, Taylor RM, Chi V, Brooks FP, Washburn S et al. Bending and buckling of carbon nanotubes under large strain. Nature 1997;389:582–4. [42] Bower C, Rosen R, Jin L, Han J, Zhou O. Deformation of carbon nanotubes in nanotube-polymer composites. Applied Physics Letters 1999;74(22):3317–9. [43] Overney G, Zhong W, Tomanek D. Structural rigidity and low frequency vibrational modes of long carbon tubules. Zeitschrift Fur Physik D-Atoms Molecules and Clusters 1993;27(1):93–6. [44] Lu JP. Elastic properties of single and multilayered nanotubes. Journal of the Physics and Chemistry of Solids 1997;58(11):1649–52. [45] Yakobson BI, Campbell MP, Brabec CJ, Bernholc J. High strain rate fracture and C-chain unraveling in carbon nanotubes. Computational Materials Science 1997;8(4):341–8. [46] Bernholc J, Brabec CJ, Nardelli M, Maiti A, Roland C, Yakobson BI. Theory of growth and mechanical properties of nanotubes. Applied Physics A-Materials Science and Processing 1998; 67(1):39–46. [47] Iijima S, Brabec C, Maiti A, Bernholc J. Structural flexibility of carbon nanotubes. Journal of Chemical Physics 1996;104(5): 2089–92. [48] Ru CQ. Effective bending stiffness of carbon nanotubes. Physical Review B 2000;62(15):9973–6. [49] Vaccarini L, Goze C, Henrard L, Hernandez E, Bernier P, Rubio A. Mechanical and electronic properties of carbon and boronnitride nanotubes. Carbon 2000;38(11-12):1681–90. [50] Al-Jishi R, Dresselhaus G. Lattice dynamical model for graphite. Physical Review B 1982;26(8):4514–22. [51] Hernandez E, Goze C, Bernier P, Rubio A. Elastic properties of C and BxCyNz composite nanotubes. Physical Review Letters 1998;80(20):4502–5. [52] Ru CQ. Elastic buckling of single-walled carbon nanotube ropes under high pressure. Physical Review B 2000;62(15):10405–8. [53] Popov VN, Van Doren VE, Balkanski M. Elastic properties of crystal of single-walled carbon nanotubes. Solid State Communications 2000;114(7):395–9. [54] Popov VN, Van Doren VE, Balkanski M. Lattice dynamics of singlewalled carbon nanotubes. Physical Review B 1999;59(13):8355–8. [55] Ruoff RS, Lorents DC. Mechanical and thermal-properties of carbon nanotubes. Carbon 1995;33(7):925–30. [56] Govindjee S, Sackman JL. On the use of continuum mechanics to estimate the properties of nanotubes. Solid State Communications 1999;110(4):227–30. [57] Ru CQ. Effect of van der Waals forces on axial buckling of a double-walled carbon nanotube. Journal of Applied Physics 2000;87(10):7227–31. [58] Ru CQ. Column buckling of multi-walled carbon nanotubes with interlayer radial displacements. Physical Review B 2000;62(24): 16962–7. [59] Ru CQ. Degraded axial buckling strain of multiwalled carbon nanotubes due to interlayer slips. Journal of Applied Physics 2001;89(6):3426–33. 1911 [60] Kolmogorov AN, Crespi VH. Smoothest bearings: interlayer sliding in multiwalled carbon nanotubes. Physical Review Letters 2000;85(22):4727–30. [61] Shaffer MSP, Windle AH. Fabrication and characterization of carbon nanotube/poly (vinyl alcohol) Composites. Advanced Materials 1999;11(11):937–41. [62] Qian D, Dickey EC, Andrews R, Rantell T. Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites. Applied Physics Letters 2000;76(20):2868–70. [63] Tibbetts GG, McHugh J. Mechanical properties of vapor-grown carbon fiber composites with thermoplastic matrices. Journal of Materials Research 1999;14:2871. [64] Jia Z, Wang Z, Xu C, Liang J, Wei B, Wu Detal. Study on poly(methyl methacrylate)/carbon nanotube composites. Materials Science and Engineering A 1999;271(1–2):395–400. [65] Gong X, Liu J, Baskaran S, Voise RD, Young JS. Surfactantassisted processing of carbon nanotube/polymer Composites. Chemistry of Materials 2000;12(4):1049–52. [66] Lordi V, Yao N. Molecular mechanics of binding in carbonnanotube-polymer composites. Journal of Materials Research 2000;15(12):2770–9. [67] Wagner HD, Lourie O, Feldman Y, Tenne R. Stress-induced fragmentation of multiwall carbon nanotubes in a polymer matrix. Applied Physics Letters 1998;72(2):188–90. [68] Lourie O, Wagner HD. Transmission electron microscopy observations of fracture of single-wall carbon nanotubes under axial tension. Applied Physics Letters 1998;73(24):3527–9. [69] Lourie O, Wagner HD. Buckling and collapse of embedded carbon nanotubes. Physical Review Letters 1998;81(8):1638– 41. [70] Lourie O, Wagner HD. Evidence of stress transfer and formation of fracture clusters in carbon nanotube-based composites. Composites Science and Technology 1999;59(6):975–7. [71] Cooper CA, Young RJ, Halsall M. Investigation into the deformation of carbon nanotubes and their composites through the use of raman spectroscopy. Composites Part A: Applied Science and Manufacturing 2001;32(3-4):401–11. [72] Ajayan PM, Schadler LS, Giannaris C, Rubio A. Single-walled nanotube-polymer composites: strength and weaknesses. advanced materials 2000;12(10):750–3. [73] Schadler LS, Giannaris SC, Ajayan PM. Load transfer in carbon nanotube epoxy composites. Applied Physics Letters 1998;73(26): 3842–4. [74] Jin L, Bower C, Zhou O. Alignment of carbon nanotubes in a polymer matrix by mechanical stretching. Applied Physics Letters 1998;73(9):1197–9. [75] Haggenmueller R, Gommans HH, Rinzler AG, Fischer JE, Winey KI. Aligned single-wall carbon nanotubes composites by melt processing methods. Chemical Physics Letters 2000;330(3-4): 219–25. [76] Gommans HH, Alldredge JW, Tashiro H, Park J, Magnuson J, Rinzler AG. Fibers of aligned single-walled carbon nanotubes: polarized raman spectroscopy. Journal of Applied Physics 2000; 88(5):2509–14. [77] Andrews R, Jacques D, Rao AM, Rantell T, Derbyshire F, Chen Yetal. Nanotube composite carbon fibers. Applied Physics Letters 1999;75(9):1329–31. ´ [78] Vigolo B, Penicaud A, Coulon C, Sauder C, Pailler R, Journet C et al. Macroscopic fibers and ribbons of oriented carbon nanotubes. Science 2000;290:1331–4. [79] Ma RZ, Wu J, Wei BQ, Liang J, Wu DH. Processing and properties of carbon nanotubes-nano-SiC ceramic. Journal of Materials Science 1998;33(21):5243–6. ` [80] Flahaut E, Peigney A, Laurent Ch, Marliere Ch, Chastel F, Rousset A. Carbon nanotube-metal-oxide nanocomposites: microstructure, electrical conductivity and mechanical properties. Acta Materialia 2000;48(14):3803–12. 1912 E.T. Thostenson et al. / Composites Science and Technology 61 (2001) 1899–1912 [84] Peigney A, Laurent Ch, Rousset A. Synthesis and characterization of alumina matrix nanocomposites containing carbon nanotubes. Key Engineering Materials 1997;132-136:743–6. [85] Chen X, Xia J, Peng J, Li W, Xie S. Carbon-nanotube metalmatrix composites prepared by electroless plating. Composites Science and Technology 2000;60(2):301–6. [86] Xu CL, Wei BQ, Ma RZ, Liang J, Ma XK, Wu DH. Fabrication of aluminum-carbon nanotube composites and their electrical properties. Carbon 1999;37(5):855–8. [81] Peigney A, Laurent Ch, Flahaut E, Rousset A. Carbon nanotubes in novel ceramic matrix nanocomposites. Ceramics International 2000;26(6):667–83. [82] Peigney A, Laurent Ch, Dumortier O, Rousset A. Carbon nanotubes-Fe-alumina nanocomposites. Part I: influence of the Fe content on the synthesis of powders. Journal of the European Ceramic Society 1998;18(14):1995–2004. [83] Peigney A, Laurent Ch, Dumortier O, Rousset A. Carbon nanotubes-Fe-alumina nanocomposites. Part II: microstructure and mechanical properties of the hot-pressed composites. Journal of the European Ceramic Society 1998;18(14):2005–13.

You May Also Find These Documents Helpful

  • Powerful Essays

    Callister, W. D. 2007, ‘Callister’s Materials Science and Engineering’, John Wiley and Sons, Inc., 605 Third Avenue, New York, USA, NY 10158-0012.…

    • 2077 Words
    • 9 Pages
    Powerful Essays
  • Satisfactory Essays

    Polymer Chains

    • 600 Words
    • 3 Pages

    2. We discussed how polymer linking and structure contribute to its properties. How would you expect the density, elasticity, and rigidity of a polymer that is branched to compare to one that is linear?…

    • 600 Words
    • 3 Pages
    Satisfactory Essays
  • Good Essays

    Hip Joint Displacement

    • 583 Words
    • 3 Pages

    This is Because CNTs has unique properties such as high aspect ratio, lightweight, high mechanical strength, good thermal and electrical conductivity and excellent tribological behavior [21]. However, the results were not favorable due to the poor compatibility of POM with other materials as a result of high viscosity, especially with bulk materials [22]. Therefore, Yousef et al. (2013) develop a paraffin oil (PO) dispersion technique to obtain a uniform dispersion. The new dispersion technique summarized on adding a small amount of PO (2-3%Wt.) during the mixing process to decrease the viscosity of POM during the injection process then obtain a uniform dispersion of CNTs inside the matrix [23]. Through the new dispersion technique, Yousef et al. (2015) succeed to produce a real CNTs/POM bulk products had a uniform dispersion, in particular, spur, helical, bevel, and worm gears [24]. The results showed that the new dispersion technique has been successfully utilized to increase the wear resistance of POM by adding 0.02 wt. % of POM by 35% when compared by virgin…

    • 583 Words
    • 3 Pages
    Good Essays
  • Satisfactory Essays

    Materials Science and Engineering: A, Volume 527, Issue 15, 15 June 2010, Pages 3536-3545 By Fabio Grosselle, Giulio Timelli, Franco Bonollo…

    • 434 Words
    • 2 Pages
    Satisfactory Essays
  • Better Essays

    Materials Lab Report

    • 1581 Words
    • 7 Pages

    Bibliography: Dowling NE (2007) Mechanical Behaviour of Materials 3 Ed. Pearson Prentice-Hall: New Jersey. Breburge B (1999) Cracks and Fracture. Academic Press: California. Gross D and Seeling T (2006) Fracture Mechanics with an Introduction to Micromechanics. Springer: Berlin. th Callister WD (2007) Materials Science and Engineering 7 ed. John Wiley and Sons, Inc: York.…

    • 1581 Words
    • 7 Pages
    Better Essays
  • Powerful Essays

    The mechanical properties of polymers vary significantly from polymer to polymer as a result of atomic structures and bond strength. The tensile properties of representative samples from the common polymer were tested and evaluated in this experiment. This laboratory experiment is also designed to demonstrate the procedure used for obtaining mechanical properties as modulus of elasticity, yield strength, ultimate tensile strength (UTS), uniform elongation, elongation and reduction in area at rupture. This report is based on the fact of understanding how tensile properties are controlled by the nature of the polymers chain and how tensile properties of polymers vary with testing speed.…

    • 2341 Words
    • 10 Pages
    Powerful Essays
  • Good Essays

    Carbon fibre reinforcement polymer (CFRP) is an extremely strong and light which contains carbon fiber. Carbon Fibre Reinforced Polymer (CFRP) composite have been widely used in various applications especially used in the fabrication of aerospace structures and formula one body structures. Because of their low density, high strength and rigidity, excellent resistances to impacting and corrosion, CFRPs are widely applicable in various important structural components. Other fibers like Kevlar, glass fibers, and aluminum may also be used along with carbon fibers. Carbon fiber reinforced polymer-matrix composites (CFRPs) are manufactured by carbon fibers and resin under specific conditions. Especially in the field of spaceflight and aviation, CFRPs are exhibiting incomparable potential.…

    • 456 Words
    • 2 Pages
    Good Essays
  • Powerful Essays

    Energy Absorbing Impact Zone

    • 5551 Words
    • 27 Pages

    References: Roylance, D. (2001), Finite Element Analysis [Internet], Available from http://ocw.mit.edu/courses/materials-science-and-engineering/3-11-mechanics-of-materials-fall-1999/modules/fea.pdf [Accessed Apr 12th 2014]…

    • 5551 Words
    • 27 Pages
    Powerful Essays
  • Better Essays

    Carbon fibre reinforced polymers despite being relative expensive as compared to other traditional metallic materials; they have been preferred for many applications such as in the automotive industry and aeronautical industry where high strength-to-weight ratio is demanded.…

    • 1406 Words
    • 4 Pages
    Better Essays
  • Satisfactory Essays

    Science (print ISSN 0036-8075; online ISSN 1095-9203) is published weekly, except the last week in December, by the…

    • 4611 Words
    • 19 Pages
    Satisfactory Essays
  • Powerful Essays

    Carbon Nanostructures

    • 1956 Words
    • 8 Pages

    Fullerene (C60): • C60 was named after the architect R. Buckminster Fuller who designed the geodesic dome that resembles the structure of C60. • C60 has 12 pentagonal (5 sided) and 20 hexagonal (6 sided) faces symmetrically arrayed to form a molecular ball. • Existence of C60 had been envisioned by theoretical chemists for years before it was experimentally confirmed by Huffiman and Kratschmer. • In fact, C60 has the same geometric…

    • 1956 Words
    • 8 Pages
    Powerful Essays
  • Good Essays

    Polyvinylchloride Case Study

    • 2931 Words
    • 12 Pages

    The treated nanoparticles cause the film to become brittle even at loadings of 2 phr and the elongation to break continues to decrease up to 5 phr. The effect of CaCO3 nano particles loading on the Young’s modulus of PVC matrix and the nanocomposites is shown in Figure 4. PVC films containing untreated nano-filler show only minor improvement of about 17% in the modulus values. Young’s modulus in nano-composites does not undergo much change in the elongation to break values; this can be associated with the disappearance of plastic deformation of the polymer…

    • 2931 Words
    • 12 Pages
    Good Essays
  • Best Essays

    Biosensors Nano

    • 3379 Words
    • 14 Pages

    References: [1] Introduction to Nanotechnology, Wiley, 2003. [2] Analyst, 2004, 129, 672. [3] Acc. Chem. Res., 1995, 28, 61. [4] ChemPhysChem, 2001, 2, 79. [5] Electroanalysis, 1997, 9, 661. [6] J. Am. Chem. Soc., 2003, 125, 9006. [7] Electrochem. Commun., 2003, 5, 408 [8] Angew Chem. Int. Ed., 2004, 43, 2113. [9] Science, 2003, 299, 1877. [10] J. Am. Chem. Soc., 2003, 125, 2408.…

    • 3379 Words
    • 14 Pages
    Best Essays
  • Powerful Essays

    Chemistry- Purifying Water

    • 1679 Words
    • 7 Pages

    They are called “Nano” because of their sizes that are roughly billion times smaller than a meter. Normally they are very thin and have hollow cylindrical structures made out of carbon atoms. However, they still exist in various shapes such as cylinders, spheres, cones, tubes and also complicated shapes. Carbon nanotubes have exceptional thermal, electrical and mechanical properties, allowing them to be widely used in numerous industries.…

    • 1679 Words
    • 7 Pages
    Powerful Essays

Related Topics